Create a web service method (example) in Jitterbit Design Studio
Create the web service method
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From the menu on the left, right click on Web Service Methods and choose New Web Service Method.  
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Name: Get Stock Quote 
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Choose Select a WSDL From a URL and enter: http://ws.cdyne.com/delayedstockquote/delayedstockquote.asmx?wsdl
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Click Next. 
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From the drop down list at the top of the next screen, Choose: GetQuote (SOAP1.1). 
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Click Next. 
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Click Finish. 
Create an operation
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Right-click on Operation and choose New Operation. 
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Choose Web Service Call as your operation type and click Continue.  
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Right click on Source and Target and remove them from the graph. 
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Drag the Web Service Call that you created in the previous step into the Middle Box.  
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Double click on the Request transformation (left) and click the CreateNew Transformation button in the dialog box. 
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Select None at the bottom of the list for the source. 
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Click Finish. 
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Expand the tree on the left side of the transformation. 
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Double click on StockSymbol field.  
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Enter "CRM" between the <trans>and</trans>tags and click OK. 
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Double-click on the LicenseKey field; enter "0" between the <trans>and</trans>tags and click OK. 
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Double-click on the Response transformation (right) and click the Create New Transformation button in the dialog box. 
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Choose XML as your target and click Next. 
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Choose Create a new XML structure from a sample file and click next. 
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Using the browse button, navigate to the sample XML file that you have been provided: Sample XML File  
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Click Generate the XSD and click Next. 
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Uncheck the box on the next screen and click finish.  
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On the transformation screen, click the Automap function to map all the fields automatically.  
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Double click on the operation name and rename it to: Get Stock Quote  
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Click OK. 
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For writing the results of the stock to the log file, view this video: 
The video Harmony Starter Pack, Part 3: How to Call a Web Service in Jitterbit demonstrates these steps: